Chemistry 323/324 Announcements

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12/17/08 Final grades have been submitted for both the lecture and the laboratory and should be available sometime after noon on 12/18.

For the lecture, I used a 0.9 multiplier on the post-exam (you could get up to 90% of the points you missed on the in-class exam back) and I added 6 points to take-home exam 2 and 8 points to take-home exam 3 (beyond the score that is written on the cover page).  This made the average for exam 2 and exam 3 be around 75% (as it was for exam 1).  The total number of points for the exams, quizzes and the final exam was then calculated, as stated in the syllabus.  I extended the grade cutoffs to 870 (A), 770 (B), 670 (C) and 570 (D) and then decided whether to move people up (which in most cases I did) or to leave them where they were (very few, if any), based on my published criteria.  It should be noted that a number of people were helped by a strong performance on the final (i. e., moved up a letter grade), and that anybody who did poorly on the final stayed where they were (i. e., the final didn't affect their final letter grade).

I made no modifications to the laboratory, other than to extend the grade cutoffs down by 10 points.  People were moved up a letter grade if they showed improvement over the semester, or if they had been hurt by a single poor grade.

FERPA forbids me from answering e-mails about grades and I will be in and out over break (and therefore harder to reach by phone than usual).  I will, however, be willing to discuss your grade when the spring semester starts and help you to improve in second semester courses.

12/5/08 The post-exam is available outside my door.  You may download a PDF version of the questions and the answer sheet by clicking here. Click here to view the rules for the post-exam. 
11/30/08 In problem 4b on the take-home portion of exam 3, I neglected to tell you that the reaction is independent of [Cr2O72-] at all [H+].  Note that you will need to show me your logic in coming up with your mechanism for full credit.  Simply writing a mechanism and deriving a rate law will not get you all the points.
11/24/08 The take-home portion of exam 3 is available, as is the Excel file containing the data (TakeHome3.xls).
11/14/08 Click here to view the rules for the post-exam.  Click here to download the post-exam questions and the answer sheet as a PDF file.

Problems and exercises for kinetics from chapter 22 (25) for the next quiz are as follows.

Exercises: 22.1 (25.5), 22.3 (25.7), 22.5 (25.9), 22.7 (25.11), 22.10 (25.14), 22.13 (25.20)

Problems: 22.1 (25.1), 22.2 (25.2), 22.3 (25.3), 22.5 (25.5), 22.8 (25.7), 22.10 (25.9), 22.11 (25.10), 22.13 (25.12), 22.23 (25.20)

11/7/08 Problems and exercises from chapter 7 (9 and 10).

Exercises: 7.1 (9.7), 7.3 (9.9), 7.6 (9.12), 7.9 (9.15), 7.13 (10.15), 7.14 (10.18), 7.16 (10.25) and 7.17 (10.26)

Problems: 7.2 (9.2), 7.13 (10.2), 7.18 (10.6) and 7.22 (10.16)

10/31/08 Click here to download a PDF version of the take-home portion of exam 2 and here to download the Excel file containing the data (TakeHome2.xls).
10/24/08 Additional problems and exercises from chapter 5 (7 and 10),

Exercises: all remaining

Problems: 5.2 (7.2), 5.4 (7.4), 5.15 (7.16) and 5.16 (10.9)

From chapter 6 (8),

Exercises: 6.3 (8.6), 6.6 (8.9) and 6.7 (8.10)

Problems: 6.1 (8.1)

10/20/08 Problems and exercises for chapter 5.

Exercises: 5.1 (7.4), 5.8 (7.12) and 5.14 (7.19)

Problems: 5.1 (7.1) and 5.7 (7.7)

10/06/08 Click here to view the rules for the post-exam.  Click here to download the post-exam questions and the answer sheet as a PDF file.
10/03/08 Because of Fall Break the next quiz will be 10/17/08.  It will draw material from what we cover in lecture through Wednesday (10/8/08) of next week (chapters 3, 4 and parts of 5).  I will post additional problems next Wednesday from chapter 5.

Chapter 4 (6)
Exercises: all

Problems: 4.8 (6.8), 4.11 (6.11) and 4.19 (6.20)

Chapter 3
Exercises: 3.1 (4.4), 3.6 (4.16), 3.7 (4.17), 3.12 (4.22) and 3.14 (4.25). For exercise 3.7 (4.17) assume that everything is reversible.

Problems: 3.9 (4.23), 3.22 (exercise 5.14b), 3.27 (5.9) and 3.28 (5.10. For problem 3.9 (4.23) the needed equation is given in the text, but it will need to be modified. For problem 3.28 (5.10) first use the definition of H and treat H as function of S and p, and for part b solve for T as a function of V.

09/29/08 Please correct the melting point of mercury on the take-home portion of exam 1.  It is 234.308 K.  This change was also made on the PDF version of the exam (on 9/29/08 at 1:51 PM).
09/26/08 Click here to download a PDF copy of the take-home portion of exam 1.  Click here to download the Excel file containing the data for problem 1.  Note this file is also available on the network at U:\_SC Student File Area\PChem\PChem1Files\.
09/22/08 Exercises: 2.28 (2.45), 2.29 (3.13), 2.30 (3.14), 2.31 (3.15)

Problems: 2.29 (3.8), 2.31 (3.21), 2.32 (3.22). For problem 2.29 (3.8) use the result given in problem 2.34 (3.24). Do problems 2.31 (3.21) and 2.32 (3.22) in the order given (the answer to the former is needed to complete the latter).

09/12/08 Exercises: 2.16 (2.29), 2.18 (2.32), 2.22 (2.40), 2.24 (2.42)

Problems: 2.1 (2.3) (hint: assume reversibility, but note that step 1 is not isothermal so you will need to use w = -pΔV), 2.12 (2.15), 2.34 (3.24).

09/08/08 Exercises: 2.2 (2.6), 2.3 (2.7), 2.4 (2.8), 2.5 (2.9)

Problems: 2.2 (2.5).

08/29/08 The problems for next week's quiz are as follows.  Note that the 8th edition numbers are given first, while the 7th edition numbers are in parentheses.  The exercises consist of two parts; one of which you have a worked solution for, the other you do not.  You should try both.

Exercises: 1.7 (1.10), 1.17 (1.21), 1.20 (1.24), 1.22 (1.26)

Problems: 1.3 (1.6), 1.15 (1.18), 1.22 (1.25), 1.24 (1.28)

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